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Electronic structure and nitrogen hybridization in .beta.-aminovinylphosphonium salts by carbon-13 nuclear magnetic resonance

✍ Scribed by Schweizer, Edward E.; Calcagno, Mark A.


Book ID
127086219
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
399 KB
Volume
42
Category
Article
ISSN
0022-3263

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## Abstract ^13^C NMR chemical shifts and ^13^Cο£Ώ^31^P couplings are reported for ten arylphosphoramidates and five arylphoshorimidates. The __para__‐carbon chemical shifts in the phosphoramidates are interpreted in terms of substantial nitrogen lone pair delocalization into the aromatic ring, a phe