Electronic structure and conformational properties of1H-indole-3-acetic acid
✍ Scribed by María C. Pérez Schmit; Alicia H. Jubert; Arturo Vitale; Rosana M. Lobayan
- Publisher
- Springer-Verlag
- Year
- 2010
- Tongue
- English
- Weight
- 497 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1610-2940
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An ab initio conformational analysis of 4-chloroindole-3-acetic acid was performed at the RHF/6-311G \* \* level. The mirror symmetrical conformer (in which the indole ring is coplanar with the COOH group) is most stable; next in energy are the two conformers with the C-COOH fragment perpendicular t
The potential energy surface of 4-methyl-3-indole acetic acid IAA was investigated via RHFr6-31G\* calculations. Five symmetry-unique local minima with syn-periplanar orientation of the COOH group are present. In contrast, unsubstituted IAA and 4-Cl-IAA have only four such minima. The shape of the e
## Abstract Labeled 1‐tryptophan is converted to indole‐3‐acetamide and then to indole‐3‐acetic acid by enzymes from __Pseudomonas savastanoi__. Labeled indole‐3‐acetic acid can be converted to indole‐3‐acetyl‐1‐__0__‐β‐D‐glucose and to indole‐3‐acetyl‐__myo__‐inositol by enzymes from kernels of __
3rd Communication, see [la]. \*) We will report on the preparation and structure of Y and related dimers