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Electronic, steric, and temperature effects in the Pd(II)-biquinoline catalyzed aerobic oxidation of benzylic alcohols in water

✍ Scribed by Brian P. Buffin; Nadine L. Belitz; Sara L. Verbeke


Book ID
104059035
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
453 KB
Volume
284
Category
Article
ISSN
1381-1169

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Mild aerobic oxidation of benzyl alcohol
✍ PaweΕ‚ J. Figiel; Alexander M. Kirillov; Yauhen Yu. Karabach; Maximilian N. Kopyl πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 279 KB

The aqua-soluble multinuclear copper(II) compounds [Cu 2 ( -H 2) (H 3 tea = triethanolamine, H 4 pma = pyromellitic acid) have been applied as efficient catalysts for the mild, selective and clean oxidation of benzyl alcohols to benzaldehydes, which proceeds in sole water as solvent at 50 β€’ C, under