Electronic spectra of diethyldithiocarbamate complexes
โ Scribed by L. M. Kurashvili; N. A. Zavorokhina
- Publisher
- Springer US
- Year
- 1974
- Tongue
- English
- Weight
- 277 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0021-9037
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๐ SIMILAR VOLUMES
Sodium salt of diethyldithiocarbamate (NaDDC) is one of the best-known organic reagents which form extractable chelates with many metal ions. Although many data on the characteristics of metal-DDC complexes have been published, no information about organometal complexes is available. In this work, t
Polarized optical spectra of three planar low-spin ds complexes, Ni(detc),, NiCl(detc) (PPh,) and Pd(detc), (where detc is diethyldithiocarbamate and PPhl is triphenylphosphine), are reported. The assignments of the spectral transitions were made based on the d-level ordering xyzyz~x2-y2rxz~z2. The