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Electronic properties of mixed-valence PtBr chains

✍ Scribed by Albers, R.C.; Alouani, M.; Wills, J.M.; Springborg, M.


Book ID
123417698
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
268 KB
Volume
42
Category
Article
ISSN
0379-6779

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Calculations of the resonance Raman excitation profiles for the v, band and its overtones have been performed for the linearchain mixed-valence platinum complex [Pt(en)\*] [Pt(en)zBr,]Br, It is found that the Pt'"-Br bond length increases by 0.075 A in the intervalence state. A satisfactory fit to t