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Electronic Interactions and Their Influence on the Conformational Stability of trans -2-Halocyclopentanol

✍ Scribed by Tormena, Cláudio F.; dos Santos, Francisco P.; Neto, Alvaro Cunha; Rittner, Roberto; Yoshinaga, Fabiana; Temistocles, Jacqueline C. T.

Book ID
126854244
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
42 KB
Volume
111
Category
Article
ISSN
1089-5639

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✍ E. Lombardi; G. Tarantini 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 659 KB

The infhrence of exchange interactions on molecular conformations is ihustrated by considering their role in stabilizing the gauche conformation of the npropylhalides. The conformational energy is c&Mated as a sum of exchange Interactions for ciusters of non-bonded atoms. The exchange component is e