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Influence of exchange interactions on molecular conformation: stability of the gauche conformers on the 2-haloethanols

✍ Scribed by E. Lombardi; G. Tarantini


Book ID
107731834
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
494 KB
Volume
60
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


Influence of exchange interactions on mo
✍ E. Lombardi; G. Tarantini 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 659 KB

The infhrence of exchange interactions on molecular conformations is ihustrated by considering their role in stabilizing the gauche conformation of the npropylhalides. The conformational energy is c&Mated as a sum of exchange Interactions for ciusters of non-bonded atoms. The exchange component is e

Effect of pressure on the conformational
✍ Seiji Sawamura; Keizo Suzuki; Yoshihiro Taniguchi 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 266 KB

IR spectra of 2-baloethanoI.s (CH2XCH20H, X = CI, Br, and I) in carbon disulfide were measured at 25°C up to 2.5 kbar. The volume changes accompanying the transformation to the Gg conformer of the compounds were -12, eO.5, and +1.3 cm3 moT' for X = Cl, Br, and I, respectively.

Influence of intermolecular interactions
✍ G. G. Malenkov; A. V. Gagua; V. P. Timofeev 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 669 KB

## Abstract Of the two known families of double‐stranded DNA conformations, A is stable in less‐polar, and __B__ in more‐polar solutions. In some water‐nonelectrolyte solutions, __B__ to __A__ transition occurs when water activity in the system is near 0.8. In such systems, however, as water‐methan