Time-resolved emission spectroscopy of 0s ( 'Z: ) and 0s ( 'As) in CCL was used to determine the rate constants kl, , b, and k+ of the triplet state (T,) sensitized formation of the 'Z:, 'As and 'Z; states of 0s. 13 sensitizers of triplet energies 140 GE,< 309 kJ mol-' were investigated. The data ar
Electronic energy transfer to dissociated bromine by O21Σ+g, 1Δg
✍ Scribed by M.A.A. Clyne; J.A. Coxon; H.W. Cruse
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 851 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Emission from a wide range of vibrational levels served during the interaction of 7 2 1)' 5 0) of the 3n(Oz) state of Br? has been obbromine at 300 K. The mechanism involves
📜 SIMILAR VOLUMES
Infrared cmisslon from HI (II = 1) and lll'(u = 2) IS observed when Hr is added to a discharged mixture of o\yp~ and hclmm. Evidence IS given that the vIbrationa modes of 1W arc evclted by E-V energy tramfcr from O&Y ' A$\_
Collisional energy transfer between '$ and 'Z: Rydberg s tates of K2 has been studied by optical-optical double resonance (OODR) resolved fluorescence spectroscopy. The collision-induced probability for transition from a '4 state to an adjacent 'Z: state of K2 depends much more strongly on AJ than o
The mechanism of electronic quenching of the A 2A state of CH by ground-state H, is qualitatively investigated by calculating the appropriate potential energy surfaces. It is shown that the appearance of an early potential barrier of 0.15 eV and of a late barrier of 0.6 eV on the potential energy su