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Electronic effects in the semiconductor - photocatalyzed oxidative cleavage of olefins

✍ Scribed by Marye Anne Fox; Chia-Chung Chen


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
219 KB
Volume
24
Category
Article
ISSN
0040-4039

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The cationic [RuCl(PNNP)] catalysts containing tetradentate ligands with a P 2 N 2 donor set (PNNP) show strong electronic effects in the cyclopropanation of para-substituted styrenes. The reactivity trend confirms that the carbene transfer to the olefin has electrophilic character. Linear free-ener