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Electronic effects in elimination reactions. VI. Bimolecular eliminations from 1-aryl-2-propyl and 2-aryl-1-propyl tosylates and bromides

โœ Scribed by DePuy, Charles H.; Storm, David L.; Frey, John T.; Naylor, Carter G.


Book ID
120377203
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
730 KB
Volume
35
Category
Article
ISSN
0022-3263

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ฮฒ-deuterium kinetic isotope effects in t
โœ Kwang-Ting Liu; Yuh Wern Wu ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue