Electronic Control of Spin Coupling in Keplerate-Type Polyoxomolybdates
✍ Scribed by Bogdan Botar; Arkady Ellern; Raphael Hermann; Paul Kögerler
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 493 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
The electron transfer reactivity of the O q O y system in low-spin 2 2 Ž . coupling is studied at the second-order unrestricted Møller᎐Plesset full r 6-311 q G\* basis set level by using different transition state structures. The properties and stabilities of the encounter complexes are compared for
## Abstract We present here a general theoretical procedure to treat the problem of electron delocalization and magnetic interactions in high‐nuclearity mixed valence clusters based on polyoxometalates. The main interactions between the delocalized electrons of mixed‐valence polyoxometalate anions