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Electronic and stereoelectronic effects on the intervalence transfer transition in biferrocene cations

โœ Scribed by LeVanda, Carole; Cowan, Dwaine O.; Bechgaard, Klaus


Book ID
126423265
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
259 KB
Volume
97
Category
Article
ISSN
0002-7863

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Optical electron transfer processes. The
โœ Robert L. Blackbourn; Joseph T. Hupp ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 618 KB

Optical electron transfer in the mixed-valence cation of biferrocenylacetylene (BF+ ) has been examined in CDIC12 solvent. The intervalence absorption line shape is relatively narrow at both low and high chromophore concentrations, but broader at intermediate concentrations. The transition energy fo