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Electronic and geometric structure of fluorine-substituted benzyl radicals

โœ Scribed by I. V. Beregovaya; L. N. Shchegoleva; V. E. Platonov

Book ID
112449055
Publisher
Springer
Year
1990
Tongue
English
Weight
519 KB
Volume
39
Category
Article
ISSN
1573-9171

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Fluorescence lifetimes of benzyl and deu
Fluorescence lifetimes of benzyl and deuterium-substituted benzyl radicals
โœ J.D. Laposa; Vincent Morrison ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 351 KB

Fluorescence lifetimes of C~KSCH~,O-,'~-,~-DC~H~CII\_~, C6HsCD&'C&~CHi, and CeD,CD+ have been me&wed at 77 K in rigid piasses. Very long decay times are obkerwd for aU the radicals. There is a dramatic deuterium af-.' feet upon ring deuceration; alkyl deuteration lengthens the lifetime if :%e phenyl