𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Electronic and conformational effects on .pi.-facial stereoselectivity in nucleophilic additions to carbonyl compounds

✍ Scribed by Wu, Yun Dong; Houk, K. N.

Book ID
120460615
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
389 KB
Volume
109
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

On the origin of Ο€-facial diastereoselec
On the origin of Ο€-facial diastereoselectivity in nucleophilic additions to chiral carbonyl compounds. 2. Calculated transition state structures for the addition of nucleophiles to propionaldehyde 1, chloroacetyldehyde 2, and 2-chloropropionaldehyde 3.
✍ G Frenking; K.F KΓΆhler; M.T Reetz πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 773 KB

Summarv : The transition state structures for addition of LiH to 1, 2, and 3 are computed and analyzed at MP2/6-3lG(d)//HF/6\_3lG(d). Three factors are found to be important for the relative energies of the transition state structures: (i) the conformational energy of the aldehyde; (ii) the interac

On the origin of Ο€-facial diastereoselec
On the origin of Ο€-facial diastereoselectivity in nucleophilic additions to chiral carbonyl compounds. 1. Rotational profiles of propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3.
✍ G Frenking; K.F KΓΆhler; M.T Reetz πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 757 KB

## SummarV : The conformational profiles for rotation around the C-C(=O) bond a and the energy minimum conformations are calculated for propionaldehyde 1, chloroacetaldehyde 2, MP2/6-3lG(d)//HF/6\_3lG(d). and 2-chloropropionaldehyde 3 at a function of a for 1, 2, The energy level of the LUMO is ca