Electronic absorption spectroscopy of [Ru(phen)2(bpy)]2+, [Ru(phen)2(dmbp)]2+, [Ru(tpy)(phen)(CH3CN)]2+ and [Ru(tpy)(dmp)(CH3CN)]2+: A theoretical study
✍ Scribed by Julien Bossert; Chantal Daniel
- Book ID
- 108082454
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 962 KB
- Volume
- 252
- Category
- Article
- ISSN
- 0010-8545
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## Abstract Polypyridyl ligand 9a,13a‐dihydro‐4,5,9,14‐tetraaza‐benzo[b]triphenylene‐11‐yl)‐phenyl‐methanone (BDPPZ) and its complexes [Ru(bpy)~2~BDPPZ]^2+^, [Ru(dmb)~2~BDPPZ]^2+^ and [Ru(phen)~2~BDPPZ]^2+^ (where bpy = 2,2′‐bipyridine, dmb = 4,4′‐dimethyl‐2,2′‐bipyridine, phen = 1,10‐phenanthrolin
## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by