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Electron Transport Across the Alkanethiol Self-assembled Monolayer/Au(111) Interface: Role of the Chemical Anchor

โœ Scribed by Lindstrom, C. D.; Muntwiler, M.; Zhu, X.-Y.


Book ID
126310856
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
74 KB
Volume
109
Category
Article
ISSN
0022-3654

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Analyses of optical frequency ellipsometric spectra obtained in situ upon completion of the self-assembly of n-alkanethiolate monolayers on gold substrates immersed in methanol reveal the presence of a 1.2 + 0.4 A thick S/Au interface layer. This layer exhibits unique optical transitions, modeled as