Electron-Transfer reactions of organometallic and coordination compounds in the absence of solvent: Experimental results and theoretical approaches
β Scribed by Paul Sharpe; Charles S. Christ; John R. Eyler; David E. Richardson
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 560 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can
## Solvent effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H20):+ at single crystal gold electrodes are also discussed. This system shows a very large double
## Abstract Solventβsolute interactions in the peroxyacid oxidations are believed to be specific rather than electrostatic in nature. The kinetic solvent effects reported for the oxidations of organic sulfides, olefins, acetylenes, nitrosobenzenes, thioketones, and aryl sulfines reveal that in each
## Abstract For Abstract see ChemInform Abstract in Full Text.
Various dithioureas bearing an aromatic ring on their terminal nitrogen atoms have been synthesized. These have been tested in the asymmetric reduction of ketones as catalyzed by a rhodium complex. The influence of electron-withdrawing and electron-donating substituents on the aromatic rings on the