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Electron transfer reactions from aromatic carbonyl triplets to paraquat dication

โœ Scribed by Paritosh K Das


Book ID
104241498
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
212 KB
Volume
22
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Facile electron transfer from aromatic t
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The bimolecular rate constants for electron transfer from aromatic triplets to polyaryl carbocations are large and diffusioncontrolled even in the limit of high exothermicity. In some cases, although the exothermicity of energy transfer is comparable to that for electron transfer, the latter dominat

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Evidence rs presented that the excited singlet and triplet states of aromatic hydrocarbons are oxidised by methyi viologen (hlV2>. Rate constants for electron transfer from triplet naphthalene, anthracene, phenanthrene and fluoranthene are close to diffusion-controlled whereas those for triplet l-cy