The bimolecular rate constants for electron transfer from aromatic triplets to polyaryl carbocations are large and diffusioncontrolled even in the limit of high exothermicity. In some cases, although the exothermicity of energy transfer is comparable to that for electron transfer, the latter dominat
โฆ LIBER โฆ
Electron transfer reactions from aromatic carbonyl triplets to paraquat dication
โ Scribed by Paritosh K Das
- Book ID
- 104241498
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 212 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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Evidence rs presented that the excited singlet and triplet states of aromatic hydrocarbons are oxidised by methyi viologen (hlV2>. Rate constants for electron transfer from triplet naphthalene, anthracene, phenanthrene and fluoranthene are close to diffusion-controlled whereas those for triplet l-cy