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Facile electron transfer from aromatic triplets to polyaryl carbocations

✍ Scribed by A. Samanta; K.R. Gopidas; P.K. Das

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
307 KB
Volume
204
Category
Article
ISSN
0009-2614

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✦ Synopsis

The bimolecular rate constants for electron transfer from aromatic triplets to polyaryl carbocations are large and diffusioncontrolled even in the limit of high exothermicity. In some cases, although the exothermicity of energy transfer is comparable to that for electron transfer, the latter dominates over the former.

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