Electron-transfer reaction of 1,2-disila-3,5-cyclohexadienes
β Scribed by Masahiro Kako; Hideki Takada; Yasuhiro Nakadaira
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 242 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Ultraviolet irradiation of the title compounds in amine solvents results in transformations attributed to initial formation of radical ions by electron transfer, the quantum efficiency of reaction depending on the ionization potential of the amine. Cross-conjugated cyclohexadienones have been the su
Addition of sulfur dioxide to conjugated dienes has been known for many years. I,2 Usually 2,5-dihydrothiophene-1,1-dioxides (sulfones) are formed. Recently334 however, two highly reactive 1,3-dienes have been reported to yield 3,6-dihydro-1,2-oxathiin-2-oxides (sultines).