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Electron transfer photochemistry of endoperoxides

โœ Scribed by Yasutake Takahashi; Shin-ichi Morishima; Tsutomu Miyashi


Book ID
103993775
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
423 KB
Volume
65
Category
Article
ISSN
1010-6030

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Time-resolved in combination with steady-state experiments reveal that aromatic endoperoxides dissociate in general in IWO steps via a biradical intermediate if excited to upper xu\* singlet states. This process is not influenced by solvent. Time constants in the picosecond domain are reported.