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Electron-Transfer Oxidation Properties of Unsaturated Fatty Acids and Mechanistic Insight into Lipoxygenases

✍ Scribed by Kitaguchi, Hironori; Ohkubo, Kei; Ogo, Seiji; Fukuzumi, Shunichi


Book ID
126973005
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
135 KB
Volume
110
Category
Article
ISSN
1089-5639

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## Abstract A proton‐coupled electron transfer (PCET) process plays an important role in the initial step of lipoxygenases to produce lipid radicals which can be oxygenated by reaction with O~2~ to yield the hydroperoxides stereoselectively. The EPR spectroscopic detection of free lipid radicals an