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Proton-Coupled Electron Transfer of Unsaturated Fatty Acids and Mechanistic Insight into Lipoxygenase

✍ Scribed by Shunichi Fukuzumi


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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Proton-Coupled Electron Transfer of Unsa
✍ Shunichi Fukuzumi πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 224 KB

## Abstract A proton‐coupled electron transfer (PCET) process plays an important role in the initial step of lipoxygenases to produce lipid radicals which can be oxygenated by reaction with O~2~ to yield the hydroperoxides stereoselectively. The EPR spectroscopic detection of free lipid radicals an