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Electron-transfer distance in intermolecular diffusion-limited reactions

โœ Scribed by Dutt, G. B.; Periasamy, N.


Book ID
121447221
Publisher
Royal Society of Chemistry
Year
1991
Tongue
English
Weight
699 KB
Volume
87
Category
Article
ISSN
0956-5000

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## AbStlWt For the quenching of 9,l Odicyanoanthracene fluorescence by a series of aromatic amines in acetonitrile, a finite-sink analysis provides values of the effective electron-transfer distance R which increase with exergonicity ( -AGO) from 420 pm for benzylamine (AGO= -0.77 eV), close to th