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Electron-transfer activation of the aminocarbyne and the hydrogen isocyanide complexes trans-[ReCl(CNHn)(Ph2PCH2CH2PPh2)2][BF4]n−1 (n=2 or 1). Interconversion of coordinated CNH2 and CNH

✍ Scribed by M.Amélia N.D.A. Lemos; M.Fátima C.Guedes da Silva; Armando J.L. Pombeiro


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
828 KB
Volume
226
Category
Article
ISSN
0020-1693

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📜 SIMILAR VOLUMES


Reversible CH Bond Activation Reactions
✍ Mark J. Chilvers; Rodolphe F. R. Jazzar; Mary F. Mahon; Michael K. Whittlesey 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 2 views

## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy