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Electron spin resonance study of the influence of the nitrogen substituent on the conformation and spin density distribution of phenothiazine derivatives

✍ Scribed by Rup�rez, Francisco L�pez; Conesa, Jose C.; Soria, Javier


Book ID
119949527
Publisher
Royal Society of Chemistry
Year
1986
Tongue
English
Weight
660 KB
Volume
3
Category
Article
ISSN
1472-779X

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The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined