Electron donation capability of the trimethylsiloxy substituent as studied by photoelectron spectroscopy and electron spin resonance of polysubstituted benzene derivatives

Radical polymerization of dicyclohexyl f

Radical polymerization of dicyclohexyl fumarate and its derivatives as studied by electron spin resonance spectroscopy

✍ Akikazu Matsumoto; Yoshinori Sano; Masahiro Yoshioka; Takayuki Otsu 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 698 KB

The radical polymerization of dicyclohexyl fumarate (DCHF) and its derivatives was carried out with dimethyl 2,2'-azobisisobutyrate in benzene at 60°C. The propagation and termination rate constants (kp and kl) were determined by electron spin resonance spectroscopy. The k, and k, values were 0.48-0