Electron spin resonance study of iron(III) and ruthenium(III) in a trinuclear complex of tris(2-mercaptoethylamine)cobalt(III)
β Scribed by DeSimone, R. E.; Ontko, T.; Wardman, L.; Blinn, E. L.
- Book ID
- 125899548
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 585 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
13C! and 'H isotropic shifts have been measured for a series of Fe(lII) fris-dithiocarbamatc complexes. The '3C isotropic shifts mny be interpreted as arising soIely from contact hyperfinc coupling and demonstrate that as the low-spin smte cf the metal is favoured there is an increase in metal-ligzn
A vibrational resonance Raman effect of the totally symmetric Fe - F stretching mode at 453 cm^β1^is observed for high-spin tetra-n-butylammonium di(fluoro)tetraphenylporphyrinatoferrate(III). Typical A-term scattering with a high intensity overtone progression is proposed to be due to coincidence o