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Electron spin resonance studies of several anion radicals of nitro-substituted thioacylpiperidines and morpholines

✍ Scribed by C. Cercasov; F. Cornea; M. Ciureanu; M. Hillebrand; V. E. Sahini; E. Volanschi

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
398 KB
Volume
20
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The radical anions of m‐ and p‐ nitro‐substituted derivatives of several classes of N‐(thioacyl)‐piperidines and ‐morpholines have been studied by ESR spectroscopy. The anion radicals were found to be centred on the nitro group, and the distribution of the unpaired electron was found to be dependent on the extent of conjugation between the thiocarbonyl group and the aromatic moiety of the molecule. The hfs constants were discussed in terms of the spin densities calculated by the McLachlan procedure.

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