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Electron spin echo study of Ti3+ in reduced Rh/Tio2

✍ Scribed by Tsuneki Ichikawa; Susumu Fujimoto; Hiroshi Yoshida

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
239 KB
Volume
103
Category
Article
ISSN
0009-2614

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✦ Synopsis

An electron spin echo study of Ti 3+ in Rh/TlOz formed by the reaction with deuterium molccuIes at room temperature reveals that no deuterium exists within 0.6 nm from Ti 3* The formation of T13* is interpreted as bemg due to electron . transfer from detiterium atoms to T14* at the boundary behveen Rh metal and T102 and subsequent stabilization of deuterium atoms by hydroxyl amons on the surface of TtOz.

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