An electron-spin resonance study of Rh2(O2CCH3) 4(H2O)2+: evidence of πRhRh ODD electron orbital

✍ Scribed by Takashi Kawamura; Hiroaki Katayama; Tokio Yamabe

• Publisher: Elsevier Science
• Year: 1986
• Tongue: English
• Weight: 333 KB
• Volume: 130
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(86)80417-1

✦ Synopsis

Rh2 ( 02CCH,) .,( H,O): dissolved in 1 mol/dmg HC104 aqueous solution gives a broad axially symmetric ESR spectrum at 4.2 K with g,, = 3.76 and g, = 1.2. The analysis of this g-tensor has shown that the odd electron is accommodated in the degenerate x*~,,~,~ orbital.