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Raman, Pre-resonance Raman and electronic spectra of [VO(biuret)(SO4)] · 3H2O

✍ Scribed by A. H. Jubert; R. Pis Diez; S. B. Etcheverry; E. J. Baran


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
405 KB
Volume
24
Category
Article
ISSN
0377-0486

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✦ Synopsis


Abstract

Information on the vibrational and electronic properties of the [VO(biuret)(SO~4~)] · 3H~2~O complex was improved in order to gain a deeper insight into the characteristics of the metal–ligand bonds. Normal Raman and pre‐resonance Raman studies were performed, which allowed a better characterization of the metal–ligand modes and a thorough analysis of the electronic spectrum. The results were also compared with theoretical semi‐empirical molecular orbital calculations.


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