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Electron solvation in alcohol-alkane mixtures

โœ Scribed by J.H. Baxendale; P.H.G. Sharpe

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
336 KB
Volume
41
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The effect of alcohol concentration on the conductivities of solutions of rz-propanol in c-hexane and iso-octane and of t-butanol iu c-hexan= foIIowin,o electron pulse irradiation, are quantitatively consistent with the existence of an equX%rium between mobile electrons in the hydrocarbon and electrons aolvated by alcohol dimers. For methanol solutions in iso-octane the observations suaest electron solvation by a larger association of alcohol molecules (CL 6).

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The time evolution of the sokated electron in a series of linear aicohok has been measured. A correlation between the time for monomer rotation TV and the solvation time r, seems to hold for the series. The mechanism of salvation is discussed with reference to the experimental data. J Following the

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We report the duect measurement of electron solvatlon tunes m methanol and ethanol. A plcosecond techmque utihzmg a laser-trqgered flash lamp and a streak camera IS used to momtor the solvation process. The relationship of the solvatlon dynamics to dlelectrx relaxation. local hestmg. and pulse-radio