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Electron Paramagnetic Resonance Spectra of planar low-spin Complexes of Cobalt(II) with Schiff's Bases. I. N,N′-ethylene-bis(salicylideneimine)-cobalt(II). Preliminary communication

✍ Scribed by Alexander von Zelewsky; Hans Fierz

Publisher: John Wiley and Sons
Year: 1973
Tongue: German
Weight: 274 KB
Volume: 56
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19730560314

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✦ Synopsis

Abstract

The anisotropic EPR. parameters of N,N′‐ethylene‐bis(salicylideneimine)‐cobalt(II), magnetically diluted with the corresponding nickel complex, have been determined from single‐crystal measurements. From these data it is concluded that in the cobalt complex d~yz~ and d differ only slightly in energy, the former being the orbital accomodating the unpaired electron in the ground state.

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