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Electron pairing and chemical bonds. On the accuracy of the electron pair model of chemical bond

โœ Scribed by Robert Ponec; Filip Uhlik


Book ID
114142056
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
869 KB
Volume
391
Category
Article
ISSN
0166-1280

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The role of electron pairing in chemical bonding stressed by the Lewis electron-pair model of the chemical bond is analyzed and discussed from the point of view of the proposal that chemical bonds are the regions of space populated roughly by two electrons and which at the same time exhibit low fluc

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## Abstract This article reports the numerical comparison of the quantities characterizing the extent of electron fluctuation and pair localization in the domains determined by the direct minimization of electron fluctuation with the domains resulting from the partitioning of the molecules based on

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Bonding in the hypervalent molecules SF , BrF , PF , and SF was studied using multicenter bond order indices and examination of the eigenvalues and the eigenvectors of the Fermi holes of the constituent atoms. Diagonalization of the Fermi holes provided quantitative validation of Musher's categoriza