preliminary study of Electron-Nuclear Double Resonance (ENDOR) has been carried out on carbonaceous pitches and their solutions. Large matrix and hyperfine ENDOR signals have been observed, the former being very sensitive to temperature, i.e. molecular motion. Measurements made over the temperature
Electron-nuclear double resonance
โ Scribed by Leonid Kulik; Wolfgang Lubitz
- Book ID
- 106505320
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 503 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0166-8595
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The direct measurements of the principal thermal expansion coefficients were carried out for the specimens of pyrolytic graphite at temperatures between 50 and 55O"C, using an apparatus with high sensitivity. Resolving power of the apparatus was f 100 A. The c-axis thermal expansion coefficient was
The intense line in Mims and Davies electron-nuclear double resonance (ENDOR) spectra due to the hyperfine interactions of an unpaired electron with distant matrix nuclei is shown to originate from a simultaneous inversion of a large number of nuclear spins by a radiofrequency pulse. Theoretical exp