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Electron ionization mass spectra of some norbornane/ene-fused 2-N-phenyliminoperhydro-1,3-oxazines

✍ Scribed by Tuula Partanen; Pirjo Vainiotalo; Géza Stájer; Kalevi Pihlaja


Book ID
112130969
Publisher
Journal of Heterocyclic Chemistry
Year
1994
Tongue
English
Weight
275 KB
Volume
31
Category
Article
ISSN
0022-152X

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Table 1. The EI mass spectra, showing peaks ≥ 5% relative abundance, of compounds 1-7, using 70 eV electrons. Compound m/z (%RA) 1 317(M, 34) 224(10) 119 (100) 91 (22) 66 (12) 43 (8) 2 315(M, 55) 314(11) 249(6) 248(4) 198(3) 133(36) 132(8) 131(20) 119(87) 118(14) 104(6) 103( 11) 92( 35) 91( 64) 90(

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## Abstract The electron impact ionization mass spectra of dipyrido [1,2‐__a__:4,3‐__d__]pyrimidinones are strongly influenced by the degree of aromaticity of the fused rings. The molecular ions of the compounds are fairly stable. The main routes of fragmentation involve formation of the [M – H]^+^