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Electron-impact studies of organometallic molecules—VIII: Some transition metal derivatives of polyfluorobenzenes

✍ Scribed by M. I. Bruce; Mair A. Thomas


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
543 KB
Volume
1
Category
Article
ISSN
1076-5174

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Electron-impact studies of organometalli
✍ M. I. Bruce 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 669 KB

The mass spectra of several fluoroalkyl, fluoroalkenyl and fluoroacyl complexes of manganese, rhenium, iron and ruthenium carbonyls are described. After loss of carbonyl groups, fluoroalkyl compounds eliminate an olefin, with formation of metal halide species. A trifluorovinyl complex shows a novel

Electron-impact studies of organometalli
✍ M. I. Bruce 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB

THE REMARKABLE stability of cyclopentadienylthallium, C,H,Tl, has aroused interest since the first reports of its synthesis from aqueous s o l u t i ~n . ~~~ It forms air-stable, pale yellow crystals, in contrast to the methyl-substituted compound, which is oxidised vigorously by air.4 This stabilit