Electron-impact studies of organometallic molecules—VIII: Some transition metal derivatives of polyfluorobenzenes
✍ Scribed by M. I. Bruce; Mair A. Thomas
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 543 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The mass spectra of several fluoroalkyl, fluoroalkenyl and fluoroacyl complexes of manganese, rhenium, iron and ruthenium carbonyls are described. After loss of carbonyl groups, fluoroalkyl compounds eliminate an olefin, with formation of metal halide species. A trifluorovinyl complex shows a novel
THE REMARKABLE stability of cyclopentadienylthallium, C,H,Tl, has aroused interest since the first reports of its synthesis from aqueous s o l u t i ~n . ~~~ It forms air-stable, pale yellow crystals, in contrast to the methyl-substituted compound, which is oxidised vigorously by air.4 This stabilit