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Electron-impact studies of organometallic molecules—VII. Some transition metal complexes derived from 3,3,3-trifluoroprop-1-yne

✍ Scribed by M. I. Bruce

Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
642 KB
Volume
1
Category
Article
ISSN
1076-5174

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Electron-impact studies of organometalli
Electron-impact studies of organometallic molecules—X. Some simple transition metal fluorocarbon complexes
✍ M. I. Bruce 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 669 KB

The mass spectra of several fluoroalkyl, fluoroalkenyl and fluoroacyl complexes of manganese, rhenium, iron and ruthenium carbonyls are described. After loss of carbonyl groups, fluoroalkyl compounds eliminate an olefin, with formation of metal halide species. A trifluorovinyl complex shows a novel