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Electron impact mass spectrometry of ethyl esters of halogenated acetic acids

✍ Scribed by Silvia Catinella; Donata Favretto; Pietro Traldi; Pierfrancesco Bravo; Fiorenza Viani


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
332 KB
Volume
27
Category
Article
ISSN
1076-5174

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✦ Synopsis


The behaviour of a series of differently halogenated acetic acid ethyl esters was studied using electron impact and metastable ion techniques. The presence of different halogens strongly influences the fragmentation pathways and also the kinetic energy release values associated with some decomposition routes. By mass-analysed ion kinetic energy spectrometry, a composite metastable peak was detected for the transition CF2BrCO+ + CF2Br+, and rationalized on the basis of two different structures for the precursor ion.


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