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Electron impact mass spectra of a series of 1-aryl-1-alkyltetrachlorocyclotriphosphazenes1

✍ Scribed by Paul J. Harris; Kenneth B. Williams


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
176 KB
Volume
19
Category
Article
ISSN
1076-5174

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Fragmentation pathways of the title compounds were studied using accurate mass measurements and collision-induced dissociation spectra. Substituents in the ortho position of the aryl group at the pyrimidine ring were found to play a special role in the electron impact (EI) induced fragmentation of t

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Table 1. The EI mass spectra, showing peaks of >5% relative abundance (RA), of compounds 1-10, using 70 eV electrons Compound m/z (% RA) 1 315(M, 55) 314(10) 161(10) 160(89) 159(13) 107(12) 106(100) 105(11) 104(9) 91(33) 77(22) 65(15) a 2 345(M, 4) 316(7) 315(19) 314(100) 190(11) 175(7) 172(5) 160(1