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Electron impact mass spectra of a series of 1-alkyl-1-hydridotetrachlorocyclotriphosphazenes1

✍ Scribed by Paul J. Harris; Robert D. Minard; Harry R. Allcock

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
164 KB
Volume
20
Category
Article
ISSN
1076-5174

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Fragmentation pathways of the title compounds under electron impact were compared to those of their (1aryl)substituted analogs reported earlier. The main fragmentation route of the M Á ions is the sulphamide N-S bond cleavage leading to [M Γ€ ArSO 2 ] ions. No loss of the alkyl substituents from the

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fragment ions can be seen, and the spectra a Series of 1-Alkyl-1-Iodo-C,H,, tert-C,H,). These compounds are the are further complicated by the chlorine ## Tetrachlorocydotriphosphazenesl first examples of phosphazene molecules that isotopomer patterns. The molecular ion in contain a phosphorus-io