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Electron impact fragmentation of binuclear crown ethers

✍ Scribed by A. I. Gren; A. V. Mazepa; O. S. Timofeev

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
169 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis

It is shown that fragmentation under electron impact of binuclear crown ethers is similar to those for crown ethers with the general formula L-crown-n except for the formation of fragment ions with mass numbers reflecting the ring sizes in binuclear crown ether molecules. The formation of these ions occurs with hydrogen atom migrations in C-H.. -0 interactions between atoms from different rings determined in the crystal state.

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