Electron energy-loss spectroscopy of tetracyanoquinodimethane, TCNQ, tetrathiafulvalene, TTF, and the salt TTF-TCNQ
β Scribed by J.J. Ritsko; L.J. Brillson; D.J. Sandman
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 358 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0038-1098
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π SIMILAR VOLUMES
The amount of charge transfer in TTF-TCNQ and related solid compleses was determined by the anzdysis of the S 2p peak shape in their X-ray photoelectron spectra. The amount of charge transfer is 0.56 i 0.05 in TTF-TCNQ. The molccular ratio of TTF+ in the TTF column is determined to be 0.71 i 0.05 in
Since the discovery [1] of the first organic metal in 1973, much attention has been devoted to the investigation of TTF, its derivatives, and analogues as electron-donor components for many charge-transfer (CT) complexes and ion-radical salts. [2] A proposed model of a unimolecular rectifier [3] inv