Low-energy electron loss spectra of naphthalene and acenaphthene deposited on a thin film ofsolid argon have been measured at a temperature of 20 K. The second triplet of acenaphthene ( 1 'Bz) could be detected at 3.74 eV, and a further triplet is tentatively assigned at 4.23 eV. The band observed b
Electron energy-loss spectroscopy of solid fluorene and biphenyl: Search for the low-lying triplet states
โ Scribed by Petra Swiderek; Marc Michaud; Georg Hohlneicher; Leon Sanche
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 525 KB
- Volume
- 187
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
High-resolution electron energy-loss spectra are reported for fluorene and biphenyl deposited on a thin film of solid argon at a temperature of 20 K. New triplet states are detected at 3.86 eV in fluorene and 3.93 eV in biphenyl. The assignment of the newly found triplet states is discussed in the framework of the composite molecule approach.
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Electron-energy-loss spectra of phenanthrene and biphenylene deposited on a thin film of solid argon have been measured at a temperature of 20 K and an incident energy of 10.5 eV. The second triplet state of phenanthrene ( 1 'A1 ) and biphenylene ( 1 3B2,) could be detected at 3.45 and 3.20 eV, resp
Transient absorption on flash excitation at 308 nm is reported for a K,SO, crystal doped with C&. T'he multi-exponential decay and Its temperature dependence, between 6 and 125 K, support the assi~ment to a metastable triplet state of the CrOj-ion with a fastest decay constant of 200 ns. An experim