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Electron-donor-acceptor orbital correlations. Cofacial isomers of the naphthalene-tetracyanoethylene system in C2v and Cs Symmetry

โœ Scribed by B. Stevens

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
293 KB
Volume
107
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

Electron-donor-acceptor ฯ€-orbital correl
Electron-donor-acceptor ฯ€-orbital correlations in cofacial isomers of the benzene-tetracyanoethylene system
โœ B. Stevens ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

Anti correlation of highest bonding with lowest antibonding r-orbitals of the benzene -TCNE complex in cofacial isomers of C2v symmetry leads to ground state stabilisation associated with EDA complex behaviour in each case. Electron-donor-acceptor systems are classified according to the sequence of