Electron donor-acceptor compounds, 44 synthesis, molecular structure, and electron-donor properties ofpseudogem-5,8,14,17-Tetrakis(dimethylamino)[3.3]paracyclophane

✍ Scribed by Staab, Heinz A. ;Gabel, GüNter ;Krieger, Claus

• Publisher: Wiley (John Wiley & Sons)
• Year: 1987
• Tongue: English
• Weight: 483 KB
• Volume: 120
• Category: Article
• ISSN: 0009-2940
• DOI: 10.1002/cber.19871200304

✦ Synopsis

The title compound 1 consisting of two N,N,N'.N'-tetramethyl-pphenylenediamine (TMPD) units in a C3.3lparacyclophane system has been synthesized starting from 2 via 3-10 and 13. The molecular structure of 1 is discussed on the basis of an X-ray structure analysis. Electron-donor properties of 1 are reported.