The synthesis of anti-[3.3]metacyclophane quinhydrones and their thermal rearrangement to c-stereoisomers are described. Charge-transfer absorptions are discussed under the aspect of different donor-acceptor orientations. We recently reported on the synthesis of e-[3.3lmetacyclophane hydrones start
Electron donor-acceptor [3.3]metacyclophanes: charge-transfer absorption of syn- and anti-isomers
✍ Scribed by Heinz A. Staab; Annelie Döhling; Claus Krieger
- Book ID
- 104216117
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 218 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
SI,~HUT~U~~: AS &:ctron donor-acceptor [3.3]metacyclophanes with dicyanoquinomethane
as acceptor unit in different sterical arrange~~rer~ts he syn-unti isumcrs 3 and 4 were synthesized. Charge-transfer interactions arc: tiiscussed with reference to the isomerisation of 4 to 3 and to the absorption spectra.
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