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Electron delocalization in mixed-valence butadienediyl-bridged diruthenium complexes

✍ Scribed by Jörg Maurer; Rainer F. Winter; Biprajit Sarkar; Stanislav Záliš


Book ID
106243653
Publisher
Springer
Year
2005
Tongue
English
Weight
538 KB
Volume
9
Category
Article
ISSN
1432-8488

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Electron delocalization in trinuclear mi
✍ S.A. Borshch; I.N. Kotov; I.B. Bersuker 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 255 KB

Possible trapped valence states in trimeric mixed-valence clusters are considered. The adiabatic potential in the space of a doubly-degenerate e vibration is calculated. Conditions under which minima with different electron distributions exist are determined. The coexistence of localized and delocal