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Electron Delocalization and Magnetic State of Doubly-Reduced Polyoxometalates

✍ Scribed by Duclusaud, Hélène; Borshch, Serguei A.

Book ID
126645408
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
121 KB
Volume
123
Category
Article
ISSN
0002-7863

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The electronic spectra of bipy-and bipyz-anions (bipy = 2, P'-bipyridine) have been measured between 5000 and 50 000 cnl-1. The observed bands which have intensities betweenf = 6.30 x lo-2 and f = 0.52 are assised on the basis of HMO and Parker-Parr calculations. It is well known that 2,2'-bypiridi